Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursors

Takashi Toyao, Kang Liang, Kenji Okada, Raffaele Ricco, Mark J. Styles, Yasuaki Tokudome, Yu Horiuchi, Anita J. Hill, Masahide Takahashi, Masaya Matsuoka, Paolo Falcaro

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Abstract

A Cu-based metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzene tricarboxylate) has been synthesized from insoluble Cu-based precursors and positioned on substrates. Patterning of HKUST-1 was achieved through a two-step process: (1) the positioning of the insoluble Cu-based ceramic precursors on substrates using a sol-gel solution, and (2) the subsequent conversion into HKUST-1 by treatments with an alcoholic solution containing 1,3,5-benzene tricarboxylic acid (H3BTC) at room temperature for 10 min. This technique has been found to be suitable for both inorganic and polymeric substrates. The HKUST-1 pattern on a polymer film can be easily bent without affecting the positioned MOFs crystals. This approach would allow for versatile and practical applications of MOFs in multifunctional platforms where the positioning of MOFs is required.

Originalspracheenglisch
Seiten (von - bis)434-441
Seitenumfang8
FachzeitschriftInorganic chemistry frontiers
Jahrgang2
Ausgabenummer5
DOIs
PublikationsstatusVeröffentlicht - 1 Mai 2015
Extern publiziertJa

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Metals
Benzene
Substrates
Tricarboxylic Acids
Polymer films
Sol-gels
Crystals
bis(1,3,5-benzenetricarboxylate)tricopper(II)
Temperature

ASJC Scopus subject areas

  • Anorganische Chemie

Dies zitieren

Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursors. / Toyao, Takashi; Liang, Kang; Okada, Kenji; Ricco, Raffaele; Styles, Mark J.; Tokudome, Yasuaki; Horiuchi, Yu; Hill, Anita J.; Takahashi, Masahide; Matsuoka, Masaya; Falcaro, Paolo.

in: Inorganic chemistry frontiers, Jahrgang 2, Nr. 5, 01.05.2015, S. 434-441.

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Toyao, T, Liang, K, Okada, K, Ricco, R, Styles, MJ, Tokudome, Y, Horiuchi, Y, Hill, AJ, Takahashi, M, Matsuoka, M & Falcaro, P 2015, 'Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursors' Inorganic chemistry frontiers, Jg. 2, Nr. 5, S. 434-441. https://doi.org/10.1039/c4qi00215f
Toyao, Takashi ; Liang, Kang ; Okada, Kenji ; Ricco, Raffaele ; Styles, Mark J. ; Tokudome, Yasuaki ; Horiuchi, Yu ; Hill, Anita J. ; Takahashi, Masahide ; Matsuoka, Masaya ; Falcaro, Paolo. / Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursors. in: Inorganic chemistry frontiers. 2015 ; Jahrgang 2, Nr. 5. S. 434-441.
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