Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursors

Takashi Toyao; Kang Liang; Kenji Okada; Raffaele Ricco; Mark J. Styles; Yasuaki Tokudome; Yu Horiuchi; Anita J. Hill; Masahide Takahashi; Masaya Matsuoka; Paolo Falcaro

doi:10.1039/c4qi00215f

Positioning of the HKUST-1 metal-organic framework (Cu₃(BTC)₂) through conversion from insoluble Cu-based precursors

Takashi Toyao, Kang Liang, Kenji Okada, Raffaele Ricco, Mark J. Styles, Yasuaki Tokudome, Yu Horiuchi, Anita J. Hill, Masahide Takahashi, Masaya Matsuoka^*, Paolo Falcaro

^*Korrespondierende/r Autor/-in für diese Arbeit

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

A Cu-based metal-organic framework (HKUST-1 or Cu₃(BTC)₂, BTC = 1,3,5-benzene tricarboxylate) has been synthesized from insoluble Cu-based precursors and positioned on substrates. Patterning of HKUST-1 was achieved through a two-step process: (1) the positioning of the insoluble Cu-based ceramic precursors on substrates using a sol-gel solution, and (2) the subsequent conversion into HKUST-1 by treatments with an alcoholic solution containing 1,3,5-benzene tricarboxylic acid (H₃BTC) at room temperature for 10 min. This technique has been found to be suitable for both inorganic and polymeric substrates. The HKUST-1 pattern on a polymer film can be easily bent without affecting the positioned MOFs crystals. This approach would allow for versatile and practical applications of MOFs in multifunctional platforms where the positioning of MOFs is required.

Originalsprache	englisch
Seiten (von - bis)	434-441
Seitenumfang	8
Fachzeitschrift	Inorganic Chemistry Frontiers
Jahrgang	2
Ausgabenummer	5
DOIs	https://doi.org/10.1039/c4qi00215f
Publikationsstatus	Veröffentlicht - 1 Mai 2015
Extern publiziert	Ja

ASJC Scopus subject areas

Anorganische Chemie

Zugriff auf Dokument

10.1039/c4qi00215f

Andere Dateien und Links

http://www.scopus.com/inward/record.url?scp=84946747284&partnerID=8YFLogxK

Dieses zitieren

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title = "Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursors",

abstract = "A Cu-based metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzene tricarboxylate) has been synthesized from insoluble Cu-based precursors and positioned on substrates. Patterning of HKUST-1 was achieved through a two-step process: (1) the positioning of the insoluble Cu-based ceramic precursors on substrates using a sol-gel solution, and (2) the subsequent conversion into HKUST-1 by treatments with an alcoholic solution containing 1,3,5-benzene tricarboxylic acid (H3BTC) at room temperature for 10 min. This technique has been found to be suitable for both inorganic and polymeric substrates. The HKUST-1 pattern on a polymer film can be easily bent without affecting the positioned MOFs crystals. This approach would allow for versatile and practical applications of MOFs in multifunctional platforms where the positioning of MOFs is required.",

author = "Takashi Toyao and Kang Liang and Kenji Okada and Raffaele Ricco and Styles, {Mark J.} and Yasuaki Tokudome and Yu Horiuchi and Hill, {Anita J.} and Masahide Takahashi and Masaya Matsuoka and Paolo Falcaro",

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AU - Toyao, Takashi

AU - Liang, Kang

AU - Okada, Kenji

AU - Ricco, Raffaele

AU - Styles, Mark J.

AU - Tokudome, Yasuaki

AU - Horiuchi, Yu

AU - Hill, Anita J.

AU - Takahashi, Masahide

AU - Matsuoka, Masaya

AU - Falcaro, Paolo

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N2 - A Cu-based metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzene tricarboxylate) has been synthesized from insoluble Cu-based precursors and positioned on substrates. Patterning of HKUST-1 was achieved through a two-step process: (1) the positioning of the insoluble Cu-based ceramic precursors on substrates using a sol-gel solution, and (2) the subsequent conversion into HKUST-1 by treatments with an alcoholic solution containing 1,3,5-benzene tricarboxylic acid (H3BTC) at room temperature for 10 min. This technique has been found to be suitable for both inorganic and polymeric substrates. The HKUST-1 pattern on a polymer film can be easily bent without affecting the positioned MOFs crystals. This approach would allow for versatile and practical applications of MOFs in multifunctional platforms where the positioning of MOFs is required.

AB - A Cu-based metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzene tricarboxylate) has been synthesized from insoluble Cu-based precursors and positioned on substrates. Patterning of HKUST-1 was achieved through a two-step process: (1) the positioning of the insoluble Cu-based ceramic precursors on substrates using a sol-gel solution, and (2) the subsequent conversion into HKUST-1 by treatments with an alcoholic solution containing 1,3,5-benzene tricarboxylic acid (H3BTC) at room temperature for 10 min. This technique has been found to be suitable for both inorganic and polymeric substrates. The HKUST-1 pattern on a polymer film can be easily bent without affecting the positioned MOFs crystals. This approach would allow for versatile and practical applications of MOFs in multifunctional platforms where the positioning of MOFs is required.

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