Nonlinear Electrophoresis of Highly Charged Nonpolarizable Particles

Soichiro Tottori, Karolis Misiunas, Ulrich F. Keyser, Douwe Jan Bonthuis

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Abstract

Nonlinear field dependence of electrophoresis in high fields has been investigated theoretically, yet experimental studies have failed to reach consensus on the effect. In this Letter, we present a systematic study on the nonlinear electrophoresis of highly charged submicron particles in applied electric fields of up to several kV/cm. First, the particles are characterized in the low-field regime at different salt concentrations and the surface charge density is estimated. Subsequently, we use microfluidic channels and video tracking to systematically characterize the nonlinear response over a range of field strengths. Using velocity measurements on the single particle level, we prove that nonlinear effects are present at electric fields and surface charge densities that are accessible in practical conditions. Finally, we show that nonlinear behavior leads to unexpected particle trapping in channels.

Originalspracheenglisch
Aufsatznummer014502
FachzeitschriftPhysical Review Letters
Jahrgang123
Ausgabenummer1
DOIs
PublikationsstatusVeröffentlicht - 1 Jul 2019

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electrophoresis
charged particles
electric fields
velocity measurement
field strength
trapping
salts

ASJC Scopus subject areas

  • !!Physics and Astronomy(all)

Dies zitieren

Nonlinear Electrophoresis of Highly Charged Nonpolarizable Particles. / Tottori, Soichiro; Misiunas, Karolis; Keyser, Ulrich F.; Bonthuis, Douwe Jan.

in: Physical Review Letters, Jahrgang 123, Nr. 1, 014502, 01.07.2019.

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Tottori, Soichiro ; Misiunas, Karolis ; Keyser, Ulrich F. ; Bonthuis, Douwe Jan. / Nonlinear Electrophoresis of Highly Charged Nonpolarizable Particles. in: Physical Review Letters. 2019 ; Jahrgang 123, Nr. 1.
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