Microstructural evolution and order-disorder transitions in mesoporous silica films studied by FTIR spectroscopy

Plinio Innocenzi, Paolo Falcaro, David Grosso, Florence Babonneau

Publikation: Beitrag in Buch/Bericht/KonferenzbandBeitrag in einem KonferenzbandForschungBegutachtung

Abstract

Silica mesoporous thin films have been synthesised with a self-assembling process employing cetyltrimethylammonium bromide as the organic template and tetraethyl orthosilicate as the silica source. Mesoporous films with Pm3n cubic phase phases have been obtained and the films have been thermally treated in air with a progressive heating schedule from as-deposited up to 1000°C. The evolution of the microstructure has been studied with transmission Fourier transformed infrared (FTIR) spectroscopy. FTIR spectra of the as-deposited films have shown the presence of cyclic species, which at temperatures larger than 350°C have been no more observed. In the 1000-1300 cm-1 region several overlapped absorption bands have been detected. In particular, the pair LO3-TO3, the cyclic species absorption bands and the pair LO4-TO4 have been resolved. These last bands, in particular, are associated with disorder-order transitions in the silica microstructure. These disorder-induced optical modes are due to the large interface area and related to bond strains. The evolution of the bands in the 1000-1300 cm-1 region has been followed with the Berreman configuration, performing the transmission FTIR analysis at 45° with respect to the normal incidence angle. The LO3 band, which in silica sol-gel films is indicative of the network condensation and is activated by scattering of the light in the pores, was resolved as a single sharp band from 250°C.

Originalspracheenglisch
TitelMaterials Research Society Symposium - Proceedings
Redakteure/-innenC Sanchez, R.M. Laine, S Yang, C.J. Brinker
Seiten271-281
Seitenumfang11
Band726
PublikationsstatusVeröffentlicht - 2002
Extern publiziertJa
VeranstaltungOrganic/Inorganic Hybrid Materials 2002 - San Francisco, CA, USA / Vereinigte Staaten
Dauer: 1 Apr 20025 Apr 2002

Konferenz

KonferenzOrganic/Inorganic Hybrid Materials 2002
LandUSA / Vereinigte Staaten
OrtSan Francisco, CA
Zeitraum1/04/025/04/02

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Order disorder transitions
Microstructural evolution
Silicon Dioxide
Infrared spectroscopy
Silica
Absorption spectra
Infrared radiation
Microstructure
Sol-gels
Condensation
Scattering
Heating
Thin films
Air
Temperature

ASJC Scopus subject areas

  • !!Electronic, Optical and Magnetic Materials

Dies zitieren

Innocenzi, P., Falcaro, P., Grosso, D., & Babonneau, F. (2002). Microstructural evolution and order-disorder transitions in mesoporous silica films studied by FTIR spectroscopy. in C. Sanchez, R. M. Laine, S. Yang, & C. J. Brinker (Hrsg.), Materials Research Society Symposium - Proceedings (Band 726, S. 271-281)

Microstructural evolution and order-disorder transitions in mesoporous silica films studied by FTIR spectroscopy. / Innocenzi, Plinio; Falcaro, Paolo; Grosso, David; Babonneau, Florence.

Materials Research Society Symposium - Proceedings. Hrsg. / C Sanchez; R.M. Laine; S Yang; C.J. Brinker. Band 726 2002. S. 271-281.

Publikation: Beitrag in Buch/Bericht/KonferenzbandBeitrag in einem KonferenzbandForschungBegutachtung

Innocenzi, P, Falcaro, P, Grosso, D & Babonneau, F 2002, Microstructural evolution and order-disorder transitions in mesoporous silica films studied by FTIR spectroscopy. in C Sanchez, RM Laine, S Yang & CJ Brinker (Hrsg.), Materials Research Society Symposium - Proceedings. Bd. 726, S. 271-281, San Francisco, CA, USA / Vereinigte Staaten, 1/04/02.
Innocenzi P, Falcaro P, Grosso D, Babonneau F. Microstructural evolution and order-disorder transitions in mesoporous silica films studied by FTIR spectroscopy. in Sanchez C, Laine RM, Yang S, Brinker CJ, Hrsg., Materials Research Society Symposium - Proceedings. Band 726. 2002. S. 271-281
Innocenzi, Plinio ; Falcaro, Paolo ; Grosso, David ; Babonneau, Florence. / Microstructural evolution and order-disorder transitions in mesoporous silica films studied by FTIR spectroscopy. Materials Research Society Symposium - Proceedings. Hrsg. / C Sanchez ; R.M. Laine ; S Yang ; C.J. Brinker. Band 726 2002. S. 271-281
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AB - Silica mesoporous thin films have been synthesised with a self-assembling process employing cetyltrimethylammonium bromide as the organic template and tetraethyl orthosilicate as the silica source. Mesoporous films with Pm3n cubic phase phases have been obtained and the films have been thermally treated in air with a progressive heating schedule from as-deposited up to 1000°C. The evolution of the microstructure has been studied with transmission Fourier transformed infrared (FTIR) spectroscopy. FTIR spectra of the as-deposited films have shown the presence of cyclic species, which at temperatures larger than 350°C have been no more observed. In the 1000-1300 cm-1 region several overlapped absorption bands have been detected. In particular, the pair LO3-TO3, the cyclic species absorption bands and the pair LO4-TO4 have been resolved. These last bands, in particular, are associated with disorder-order transitions in the silica microstructure. These disorder-induced optical modes are due to the large interface area and related to bond strains. The evolution of the bands in the 1000-1300 cm-1 region has been followed with the Berreman configuration, performing the transmission FTIR analysis at 45° with respect to the normal incidence angle. The LO3 band, which in silica sol-gel films is indicative of the network condensation and is activated by scattering of the light in the pores, was resolved as a single sharp band from 250°C.

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