Forming Rb+ snowballs in the center of He nanodroplets

Moritz Theisen*, Florian Lackner, Wolfgang E. Ernst

*Korrespondierende/r Autor/-in für diese Arbeit

Publikation: Beitrag in einer FachzeitschriftArtikelBegutachtung

Abstract

Helium nanodroplets doped with rubidium atoms are ionized by applying a resonant two-step ionization scheme. Subsequent immersion of rubidium ions is observed in time-of-flight mass spectra. While alkali-metal atoms usually desorb from the surface of a helium nanodroplet upon electronic excitation, rubidium in its excited 52P1/2 state provides an exception from this rule (Auböck et al., Phys. Rev. Lett., 2008, 101, 35301). In our new experiment, Rb atoms are selectively excited either to the 52P 1/2 or to the 52P3/2 state. From there they are ionized by a laser pulse. Time-of-flight mass spectra of the ionization products reveal that the intermediate population of the 52P 1/2 state does not only make the ionization process Rb-monomer selective, but also gives rise to a very high yield of Rb+-He N complexes. Ions with masses of up to several thousand amu have been monitored, which can be explained by an immersion of the single Rb ion into the He nanodroplet, where most likely a snowball is formed in the center of the He nanodroplet. As the most stable position for an ion is in the center of a He nanodroplet, our results agree well with theory.

Originalspracheenglisch
Seiten (von - bis)14861-14863
Seitenumfang3
FachzeitschriftPhysical Chemistry, Chemical Physics
Jahrgang12
Ausgabenummer45
DOIs
PublikationsstatusVeröffentlicht - 7 Dez. 2010

ASJC Scopus subject areas

  • Physik und Astronomie (insg.)
  • Physikalische und Theoretische Chemie

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