Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramic

Takashi Toyao, Mark J. Styles, Tokuichiro Yago, Muhammad Munir Sadiq, Raffaele Riccò, Kiyonori Suzuki, Yu Horiuchi, Masahide Takahashi, Masaya Matsuoka, Paolo Falcaro

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Abstract

Nanocomposites obtained by integrating iron oxide magnetic nanoparticles (Fe3O4) into a metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzenetricarboxylate) are synthesized through conversion from a composite of a Cu-based ceramic material and Fe3O4. In situ small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS) measurements reveal that the presence of Fe3O4 leads to the fast conversion and synthesis of HKUST-1 with small particle sizes. The prepared MOF composite (Fe3O4@HKUST-1) is found to catalyze the one-pot sequential deacetalization-Knoevenagel condensation reaction as a magnetically collectable and recyclable catalyst. In addition, Pd nanoparticles are also incorporated into the material (Pd/Fe3O4@HKUST-1) by addition of a Pd colloidal solution during the conversion of the precursor composite to HKUST-1. The resulting Pd/Fe3O4@HKUST-1 can be utilized for hydrogenation of 1-octene in the liquid phase.

Originalspracheenglisch
Seiten (von - bis)4201-4210
Seitenumfang10
FachzeitschriftCrystEngComm
Jahrgang19
Ausgabenummer29
DOIs
PublikationsstatusVeröffentlicht - 2017

Fingerprint

ceramics
X ray scattering
catalysts
Catalysts
composite materials
Composite materials
Nanoparticles
nanoparticles
Condensation reactions
Ceramic materials
scattering
Iron oxides
iron oxides
Hydrogenation
hydrogenation
Nanocomposites
nanocomposites
liquid phases
x rays
condensation

ASJC Scopus subject areas

  • !!Chemistry(all)
  • !!Materials Science(all)
  • !!Condensed Matter Physics

Dies zitieren

Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramic. / Toyao, Takashi; Styles, Mark J.; Yago, Tokuichiro; Sadiq, Muhammad Munir; Riccò, Raffaele; Suzuki, Kiyonori; Horiuchi, Yu; Takahashi, Masahide; Matsuoka, Masaya; Falcaro, Paolo.

in: CrystEngComm , Jahrgang 19, Nr. 29, 2017, S. 4201-4210.

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Toyao, T, Styles, MJ, Yago, T, Sadiq, MM, Riccò, R, Suzuki, K, Horiuchi, Y, Takahashi, M, Matsuoka, M & Falcaro, P 2017, 'Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramic' CrystEngComm , Jg. 19, Nr. 29, S. 4201-4210. https://doi.org/10.1039/c7ce00390k
Toyao, Takashi ; Styles, Mark J. ; Yago, Tokuichiro ; Sadiq, Muhammad Munir ; Riccò, Raffaele ; Suzuki, Kiyonori ; Horiuchi, Yu ; Takahashi, Masahide ; Matsuoka, Masaya ; Falcaro, Paolo. / Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramic. in: CrystEngComm . 2017 ; Jahrgang 19, Nr. 29. S. 4201-4210.
@article{7406cdf424514eaf9f8bbb9e4ce864a6,
title = "Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramic",
abstract = "Nanocomposites obtained by integrating iron oxide magnetic nanoparticles (Fe3O4) into a metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzenetricarboxylate) are synthesized through conversion from a composite of a Cu-based ceramic material and Fe3O4. In situ small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS) measurements reveal that the presence of Fe3O4 leads to the fast conversion and synthesis of HKUST-1 with small particle sizes. The prepared MOF composite (Fe3O4@HKUST-1) is found to catalyze the one-pot sequential deacetalization-Knoevenagel condensation reaction as a magnetically collectable and recyclable catalyst. In addition, Pd nanoparticles are also incorporated into the material (Pd/Fe3O4@HKUST-1) by addition of a Pd colloidal solution during the conversion of the precursor composite to HKUST-1. The resulting Pd/Fe3O4@HKUST-1 can be utilized for hydrogenation of 1-octene in the liquid phase.",
author = "Takashi Toyao and Styles, {Mark J.} and Tokuichiro Yago and Sadiq, {Muhammad Munir} and Raffaele Ricc{\`o} and Kiyonori Suzuki and Yu Horiuchi and Masahide Takahashi and Masaya Matsuoka and Paolo Falcaro",
year = "2017",
doi = "10.1039/c7ce00390k",
language = "English",
volume = "19",
pages = "4201--4210",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "29",

}

TY - JOUR

T1 - Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramic

AU - Toyao, Takashi

AU - Styles, Mark J.

AU - Yago, Tokuichiro

AU - Sadiq, Muhammad Munir

AU - Riccò, Raffaele

AU - Suzuki, Kiyonori

AU - Horiuchi, Yu

AU - Takahashi, Masahide

AU - Matsuoka, Masaya

AU - Falcaro, Paolo

PY - 2017

Y1 - 2017

N2 - Nanocomposites obtained by integrating iron oxide magnetic nanoparticles (Fe3O4) into a metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzenetricarboxylate) are synthesized through conversion from a composite of a Cu-based ceramic material and Fe3O4. In situ small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS) measurements reveal that the presence of Fe3O4 leads to the fast conversion and synthesis of HKUST-1 with small particle sizes. The prepared MOF composite (Fe3O4@HKUST-1) is found to catalyze the one-pot sequential deacetalization-Knoevenagel condensation reaction as a magnetically collectable and recyclable catalyst. In addition, Pd nanoparticles are also incorporated into the material (Pd/Fe3O4@HKUST-1) by addition of a Pd colloidal solution during the conversion of the precursor composite to HKUST-1. The resulting Pd/Fe3O4@HKUST-1 can be utilized for hydrogenation of 1-octene in the liquid phase.

AB - Nanocomposites obtained by integrating iron oxide magnetic nanoparticles (Fe3O4) into a metal-organic framework (HKUST-1 or Cu3(BTC)2, BTC = 1,3,5-benzenetricarboxylate) are synthesized through conversion from a composite of a Cu-based ceramic material and Fe3O4. In situ small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS) measurements reveal that the presence of Fe3O4 leads to the fast conversion and synthesis of HKUST-1 with small particle sizes. The prepared MOF composite (Fe3O4@HKUST-1) is found to catalyze the one-pot sequential deacetalization-Knoevenagel condensation reaction as a magnetically collectable and recyclable catalyst. In addition, Pd nanoparticles are also incorporated into the material (Pd/Fe3O4@HKUST-1) by addition of a Pd colloidal solution during the conversion of the precursor composite to HKUST-1. The resulting Pd/Fe3O4@HKUST-1 can be utilized for hydrogenation of 1-octene in the liquid phase.

UR - http://www.scopus.com/inward/record.url?scp=85026539318&partnerID=8YFLogxK

U2 - 10.1039/c7ce00390k

DO - 10.1039/c7ce00390k

M3 - Article

VL - 19

SP - 4201

EP - 4210

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 29

ER -