Electrochemical properties of arylsilanes

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Abstract

In the past, the electrochemical properties of organosilicon compounds were investigated for both fundamental reasons and synthesis purposes. Little is, however, known about the electrochemical behaviour of hydrogen-bearing arylsilanes. Here, we throw light on the electrochemical properties of 11 arylsilanes compounds, 2 of them synthesized for the first time. The oxidation potentials are found to depend on both the nature and number of the aryl groups. Based on these findings it was possible to establish some variation trends that match the expected structure–property correlations. Furthermore, we present first insights into the electrochemical reaction kinetics behind and identify several soluble electrochemical oxidation products.

Originalspracheenglisch
Seiten (von - bis)13-18
Seitenumfang6
FachzeitschriftElectrochemistry communications
Jahrgang102
DOIs
PublikationsstatusVeröffentlicht - 1 Mai 2019

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Electrochemical properties
Organosilicon Compounds
Bearings (structural)
Electrochemical oxidation
Reaction kinetics
Hydrogen
Oxidation

Schlagwörter

    ASJC Scopus subject areas

    • !!Electrochemistry

    Dies zitieren

    Electrochemical properties of arylsilanes. / Biedermann, Judith; Wilkening, H. Martin R.; Uhlig, Frank; Hanzu, Ilie.

    in: Electrochemistry communications, Jahrgang 102, 01.05.2019, S. 13-18.

    Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

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    AU - Wilkening, H. Martin R.

    AU - Uhlig, Frank

    AU - Hanzu, Ilie

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    AB - In the past, the electrochemical properties of organosilicon compounds were investigated for both fundamental reasons and synthesis purposes. Little is, however, known about the electrochemical behaviour of hydrogen-bearing arylsilanes. Here, we throw light on the electrochemical properties of 11 arylsilanes compounds, 2 of them synthesized for the first time. The oxidation potentials are found to depend on both the nature and number of the aryl groups. Based on these findings it was possible to establish some variation trends that match the expected structure–property correlations. Furthermore, we present first insights into the electrochemical reaction kinetics behind and identify several soluble electrochemical oxidation products.

    KW - Arylsilanes

    KW - Fluorination

    KW - Kinetics

    KW - Oxidation potential

    KW - Synthesis

    KW - Thermodynamics

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