Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap

Ivo Stassen, Mark Styles, Tom Van Assche, Nicolò Campagnol, Jan Fransaer, Joeri Denayer, Jin Chong Tan, Paolo Falcaro, Dirk De Vos, Rob Ameloot

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Abstract

Film deposition is an enabling technology for integration of novel functional materials into real-world practical applications. We report both the anodic and cathodic electrochemical film deposition of UiO-66, a prototype of highly stable, zirconium-based metal-organic frameworks, using zirconium foil as the only metal source. The fundamentally different film formation mechanisms at the cathode and anode result in a significantly different coating adhesion strength, mainly due to the formation of an oxide film serving as a bridging layer at the anode. The patterned deposition capability of the electrochemical method enables the straightforward integration of UiO-66 as a sorbent film in a miniaturized sorbent trap for online analytical sampling and concentration of dilute volatile organic compounds.

Originalspracheenglisch
Seiten (von - bis)1801-1807
Seitenumfang7
FachzeitschriftChemistry of Materials
Jahrgang27
Ausgabenummer5
DOIs
PublikationsstatusVeröffentlicht - 10 Mär 2015
Extern publiziertJa

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Sorbents
Zirconium
Metals
Anodes
Volatile Organic Compounds
Functional materials
Bond strength (materials)
Volatile organic compounds
Metal foil
Oxide films
Cathodes
Sampling
Coatings

ASJC Scopus subject areas

  • !!Materials Chemistry
  • !!Chemical Engineering(all)
  • !!Chemistry(all)

Dies zitieren

Stassen, I., Styles, M., Van Assche, T., Campagnol, N., Fransaer, J., Denayer, J., ... Ameloot, R. (2015). Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap. Chemistry of Materials, 27(5), 1801-1807. https://doi.org/10.1021/cm504806p

Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap. / Stassen, Ivo; Styles, Mark; Van Assche, Tom; Campagnol, Nicolò; Fransaer, Jan; Denayer, Joeri; Tan, Jin Chong; Falcaro, Paolo; De Vos, Dirk; Ameloot, Rob.

in: Chemistry of Materials, Jahrgang 27, Nr. 5, 10.03.2015, S. 1801-1807.

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Stassen, I, Styles, M, Van Assche, T, Campagnol, N, Fransaer, J, Denayer, J, Tan, JC, Falcaro, P, De Vos, D & Ameloot, R 2015, 'Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap' Chemistry of Materials, Jg. 27, Nr. 5, S. 1801-1807. https://doi.org/10.1021/cm504806p
Stassen, Ivo ; Styles, Mark ; Van Assche, Tom ; Campagnol, Nicolò ; Fransaer, Jan ; Denayer, Joeri ; Tan, Jin Chong ; Falcaro, Paolo ; De Vos, Dirk ; Ameloot, Rob. / Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap. in: Chemistry of Materials. 2015 ; Jahrgang 27, Nr. 5. S. 1801-1807.
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