Condensation Reactions of Chlorophosphanes with Chalcogenides.

Sivathmeehan Yogendra, Saurabh S. Chitnis, Felix Hennersdorf, Michael Bodensteiner, Roland Fischer, Neil Burford, Jan J. Weigand

Publikation: Beitrag in einer FachzeitschriftArtikelBegutachtung

Abstract

A high-yielding and facile synthesis for diphosphane monochalcogenides (1Ch(R)) and their constitutional isomers, diphosphanylchalcoganes (2Ch(R)), was developed, featuring a condensation reaction between chlorophosphanes (R2PCl) and sodium chalcogenides (Na2Ch, Ch = S, Se, (Te)). The optimized protocol selectively yields either 1Ch(R) (R2(Ch)PPR2) or 2Ch(R) (Ch(PR2)2) depending upon the steric demand of the substituents R. Reaction pathways consistent with the distinct reaction outcomes are proposed. The application of 1Ch(R) and 2Ch(R) as an interesting class of ligands is exemplarily demonstrated by the prepn. of selected transition metal complexes. [on SciFinder(R)]
Originalspracheenglisch
Seiten (von - bis)1854-1860
Seitenumfang7
FachzeitschriftInorganic Chemistry
Jahrgang55
Ausgabenummer4
DOIs
PublikationsstatusVeröffentlicht - 2016

Schlagwörter

  • diphosphine monochalcogenide prepn crystal structure reaction iron
  • crystal structure diphosphine monochalcogenide diphosphinylchalcogane
  • mol structure diphosphine monochalcogenide diphosphinylchalcogane
  • phosphinylchalcogane prepn crystal structure reaction silver complex

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